Knowledge Management System Of Guangzhou Institute of Geochemistry，CAS
| Wen, Lanxuan1; Li, Xiaoping1; Na, Yun4; Chen, Huanyu1; Liu, Meng1; Yang, Shengjiong5; Ding, Dahu6; Wang, Gen5; Liu, Yu1; Chen, Yang1; Chen, Rongzhi1,2,3 | |
| Surface reconstructed Fe@C1000 for enhanced Fenton-like catalysis: Sustainable ciprofloxacin degradation and toxicity reduction | |
| Source Publication | ENVIRONMENTAL POLLUTION
 |
| ISSN | 0269-7491 |
| 2024-03-15 | |
| Volume | 345Pages:10 |
| DOI | 10.1016/j.envpol.2024.123534 |
| Language | 英语 |
| WOS Research Area | Environmental Sciences & Ecology |
| Abstract | The Fe-based catalysts typically undergo severe problems such as deactivation and Fe sludge emission during the peroxymonosulfate (PMS) activation, which commonly leads to poor operation and secondary pollution. Herein, an S-doped Fe-based catalyst with a core-shell structure (Fe@C-T, T = 1000 degrees C) was synthesized, which can solve the above issues via the dynamic surface evolution during the reaction process. Specifically, the Fe-0 on the surface of Fe@C-1000 could be consumed rapidly, leaving numerous pores; the Fe3C from the core would subsequently migrate to the surface of Fe@C-1000, replenishing the consumed active Fe species. The X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses demonstrated that the reaction surface reconstructed during the PMS activation, which involved the Fe-III in-situ reduction by S species as well as the depletion/replenishment of effective Fe species. The reconstructed Fe@C-1000 achieved near-zero Fe sludge emission (from 0.59 to 0.08-0.23 mg L-1) during 5 cycles and enabled the dynamic evolution of dominant reactive oxygen species (ROS) from SO4 |
| Keyword | Peroxymonosulfate FeIV=O Ciprofloxacin Surface reconstruction Toxicity reduction |
| WOS ID | WOS:001185542500001 |
| Indexed By | SCI |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.gig.ac.cn/handle/344008/77170 |
| Collection | 有机地球化学国家重点实验室 |
| Corresponding Author | Chen, Rongzhi |
| Affiliation | 1.Univ Chinese Acad Sci, Coll Resources & Environm, Yanshan Earth Crit Zone & Surface Fluxes Res Stn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, State Key Lab Organ Geochem, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Key Lab Environm Protect & Resources Uti, Guangzhou 510640, Peoples R China 4.Qinghai Prov Ecol Environm Planning & Environm Pro, 116 Nanshan East Rd, Xining 810007, Peoples R China 5.Xi An Univ Architecture & Technol, Key Lab Environm Engn, 13 Yanta Rd, Xian 710055, Shaanxi, Peoples R China 6.Nanjing Agr Univ, Coll Resources & Environm Sci, Nanjing 210095, Peoples R China |
| Recommended Citation GB/T 7714 | Wen, Lanxuan,Li, Xiaoping,Na, Yun,et al. Surface reconstructed Fe@C1000 for enhanced Fenton-like catalysis: Sustainable ciprofloxacin degradation and toxicity reduction[J]. ENVIRONMENTAL POLLUTION,2024,345:10. |
| APA | Wen, Lanxuan.,Li, Xiaoping.,Na, Yun.,Chen, Huanyu.,Liu, Meng.,...&Chen, Rongzhi.(2024).Surface reconstructed Fe@C1000 for enhanced Fenton-like catalysis: Sustainable ciprofloxacin degradation and toxicity reduction.ENVIRONMENTAL POLLUTION,345,10. |
| MLA | Wen, Lanxuan,et al."Surface reconstructed Fe@C1000 for enhanced Fenton-like catalysis: Sustainable ciprofloxacin degradation and toxicity reduction".ENVIRONMENTAL POLLUTION 345(2024):10. |
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