GIG OpenIR  > 同位素地球化学国家重点实验室
Zhang, Le1,2; Li, Jie1,2; Zhang, Yan3; Peng, Bing-Yu1,2; Wang, Zhi-Bing1,2; Ren, Zhong-Yuan1,2
Molybdenum isotopic fractionation in the Panzhihua mafic layered intrusion in the Emeishan large igneous province, southwest China
Source PublicationAMERICAN MINERALOGIST
ISSN0003-004X
2024-03-25
Volume109Issue:3Pages:628-632
DOI10.2138/am-2023-9154
Language英语
WOS Research AreaGeochemistry & Geophysics ; Mineralogy
AbstractThe large Mo isotopic fractionations between diferent geological reservoirs make this isotopic system a potentially useful tool for constraining the origins of magmatism. However, the efect of magmatic diferentiation on Mo isotopes is still controversial. In this study, we obtained Mo isotope data for the Panzhihua gabbroic intrusion (i.e., including mineral separates of clinopyroxene, plagioclase, magnetite, and ilmenite). The whole-rock samples and mineral separates exhibit large Mo isotopic fractionations with delta Mo-98/95 values as follows: magnetite (-0.73 parts per thousand to -0.32 parts per thousand ) < clinopyroxene (-0.32 parts per thousand to -0.10 parts per thousand ) < ilmenite (0.06 parts per thousand to 0.36 parts per thousand ) < plagioclase (0.33 parts per thousand to 0.83 parts per thousand ). Iron-Ti oxides have Mo contents that are one order of magnitude higher than those of clinopyroxene and plagioclase. Mass balance calculations based on Mo isotopes and contents are consistent with an accumulated origin for the Panzhihua intrusion. Rayleigh fractionation modeling shows that the removal of magnetite and ilmenite results in significant Mo isotopic fractionation in the residual magma. Due to the low Mo contents of clinopyroxene and plagioclase, Mo isotopes are not significantly fractionated by the removal of these minerals. Therefore, our study highlights that fractionation of Fe-Ti oxides can cause considerable Mo isotopic fractionation; consequently, caution is needed when using Mo isotopes to infer magma origins.
KeywordMo isotope fractionation magmatic differentiation Panzhihua intrusion Emeishan large igneous province Isotopes, Minerals, and Petrology Honoring John Valley
WOS IDWOS:001183294700020
Indexed BySCI
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Document Type期刊论文
Identifierhttp://ir.gig.ac.cn/handle/344008/77137
Collection同位素地球化学国家重点实验室
Corresponding AuthorZhang, Le
Affiliation1.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Isotope Geochem, Guangzhou 510640, Peoples R China
2.CAS Ctr Excellence Deep Earth Sci, Guangzhou 510640, Peoples R China
3.Minist Nat Resources, Inst Oceanog 1, Key Lab Marine Geol & Metallogeny, Qingdao 266061, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Le,Li, Jie,Zhang, Yan,et al. Molybdenum isotopic fractionation in the Panzhihua mafic layered intrusion in the Emeishan large igneous province, southwest China[J]. AMERICAN MINERALOGIST,2024,109(3):628-632.
APA Zhang, Le,Li, Jie,Zhang, Yan,Peng, Bing-Yu,Wang, Zhi-Bing,&Ren, Zhong-Yuan.(2024).Molybdenum isotopic fractionation in the Panzhihua mafic layered intrusion in the Emeishan large igneous province, southwest China.AMERICAN MINERALOGIST,109(3),628-632.
MLA Zhang, Le,et al."Molybdenum isotopic fractionation in the Panzhihua mafic layered intrusion in the Emeishan large igneous province, southwest China".AMERICAN MINERALOGIST 109.3(2024):628-632.
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