Knowledge Management System Of Guangzhou Institute of Geochemistry，CAS
| Morita, Mayu1; Yui, Hiroharu2; Urashima, Shu-hei2; Onose, Morihiko1; Komatani, Shintaro1; Nakai, Izumi3; Abe, Yoshinari4; Terada, Yasuko5; Homma, Hisashi6; Motomura, Kazuko7; Ichida, Kiyohiro1; Yokoyama, Tetsuya8; Nagashima, Kazuhide9; Aleon, Jerome10; Alexander, Conel M. O'D.11; Amari, Sachiko12,13,14; Amelin, Yuri15; Bajo, Ken-ichi16; Bizzarro, Martin17; Bouvier, Audrey18; Carlson, Richard W.11; Chaussidon, Marc19; Choi, Byeon-Gak20; Dauphas, Nicolas21,22; Davis, Andrew M.21,22; Fujiya, Wataru23; Fukai, Ryota24; Gautam, Ikshu8; Haba, Makiko K.8; Hibiya, Yuki25; Hidaka, Hiroshi26; Hoppe, Peter27; Huss, Gary R.9; Iizuka, Tsuyoshi28; Ireland, Trevor R.29; Ishikawa, Akira8; Itoh, Shoichi30; Kawasaki, Noriyuki16; Kita, Noriko T.31; Kitajima, Kouki31; Kleine, Thorsten32; Krot, Sasha9; Liu, Ming-Chang33; Masuda, Yuki8; Moynier, Frederic19; Nguyen, Ann34; Nittler, Larry11; Pack, Andreas35; Park, Changkun36; Piani, Laurette37; Qin, Liping38; Di Rocco, Tommaso35; Russell, Sara S.39; Sakamoto, Naoya40; Schonbachler, Maria41; Tafla, Lauren33; Tang, Haolan33; Terada, Kentaro42; Usui, Tomohiro24; Wada, Sohei16; Wadhwa, Meenakshi43; Walker, Richard J.44; Yamashita, Katsuyuki45; Yin, Qing-Zhu46; Yoneda, Shigekazu47; Young, Edward D.33; Zhang, Ai-Cheng48; Nakamura, Tomoki49; Naraoka, Hiroshi50; Noguchi, Takaaki30; Okazaki, Ryuji50; Sakamoto, Kanako24; Yabuta, Hikaru51; Abe, Masanao24; Miyazaki, Akiko24; Nakato, Aiko24; Nishimura, Masahiro24; Okada, Tatsuaki24; Yada, Toru24; Yogata, Kasumi24; Nakazawa, Satoru24; Saiki, Takanao24; Tanaka, Satoshi24; Terui, Fuyuto52; Tsuda, Yuichi24; Watanabe, Sei-ichiro26; Yoshikawa, Makoto24; Tachibana, Shogo53; Yurimoto, Hisayoshi16 | |
| Analysis of Cation Composition in Dolomites on the Intact Particles Sampled from Asteroid Ryugu | |
| Source Publication | ANALYTICAL CHEMISTRY
 |
| ISSN | 0003-2700 |
| 2023-12-29 | |
| Volume | 96Issue:1Pages:170-178 |
| DOI | 10.1021/acs.analchem.3c03463 |
| Language | 英语 |
| WOS Research Area | Chemistry |
| Abstract | Characterization of the elemental distribution of samples with rough surfaces has been strongly desired for the analysis of various natural and artificial materials. Particularly for pristine and rare analytes with micrometer sizes embedded on specimen surfaces, non-invasive and matrix effect-free analysis is required without surface polishing treatment. To satisfy these requirements, we proposed a new method employing the sequential combination of two imaging modalities, i.e., microenergy-dispersive X-ray fluorescence (micro-XRF) and Raman micro-spectroscopy. The applicability of the developed method is tested by the quantitative analysis of cation composition in micrometer-sized carbonate grains on the surfaces of intact particles sampled directly from the asteroid Ryugu. The first step of micro-XRF imaging enabled a quick search for the sparsely scattered and micrometer-sized carbonates by the codistributions of Ca2+ and Mn2+ on the Mg2+- and Fe2+-rich phyllosilicate matrix. The following step of Raman micro-spectroscopy probed the carbonate grains and analyzed their cation composition (Ca2+, Mg2+, and Fe2+ + Mn2+) in a matrix effect-free manner via the systematic Raman shifts of the lattice modes. The carbonates were basically assigned to ferroan dolomite bearing a considerable amount of Fe2+ + Mn2+ at around 10 atom %. These results are in good accordance with the assignments reported by scanning electron microscopy-energy-dispersive X-ray spectroscopy, where the thin-sectioned and surface-polished Ryugu particles were applicable. The proposed method requires neither sectioning nor surface polishing; hence, it can be applied to the remote sensing apparatus on spacecrafts and planetary rovers. Furthermore, the non-invasive and matrix effect-free characterization will provide a reliable analytical tool for quantitative analysis of the elemental distribution on the samples with surface roughness and chemical heterogeneity at a micrometer scale, such as art paintings, traditional crafts with decorated shapes, as well as sands and rocks with complex morphologies in nature. |
| WOS ID | WOS:001139548100001 |
| Indexed By | SCI |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.gig.ac.cn/handle/344008/76083 |
| Collection | 中国科学院广州地球化学研究所 |
| Corresponding Author | Yui, Hiroharu |
| Affiliation | 1.Horiba Techno Serv Co Ltd, Analyt Technol Div, Kyoto 6018125, Japan 2.Tokyo Univ Sci, Dept Chem, Tokyo 1628601, Japan 3.Tokyo Univ Sci, Dept Appl Chem, Tokyo 1628601, Japan 4.Tokyo Denki Univ, Grad Sch Engn Mat Sci & Engn, Tokyo 1208551, Japan 5.Japan Synchrotron Radiat Res Inst, Spect & Imaging Div, Sayo, Hyogo 6795198, Japan 6.Rigaku Corp, Osaka Applicat Lab, Osaka 5691146, Japan 7.Rigaku Corp, Thermal Anal Div, Tokyo 1968666, Japan 8.Tokyo Inst Technol, Dept Earth & Planetary Sci, Tokyo 1528551, Japan 9.Univ Hawaii Manoa, Hawaii Inst Geophys & Planetol, Honolulu, HI 96822 USA 10.Sorbonne Univ, Inst Mineral Phys Mat & Cosmochim, Museum Natl Hist Nat, Ctr Natl Rech Sci,Inst Rech Dev,Unite Mixte Rech, F-75005 Paris, France 11.Carnegie Inst Sci, Earth & Planets Lab, Washington, DC 20015 USA 12.Washington Univ, McDonnell Ctr Space Sci, St Louis, MO 63130 USA 13.Washington Univ, Phys Dept, St Louis, MO 63130 USA 14.Univ Tokyo, Geochem Res Ctr, Tokyo 1130033, Japan 15.Chinese Acad Sci, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China 16.Hokkaido Univ, Dept Nat Hist Sci, Sapporo 0010021, Japan 17.Univ Copenhagen, Ctr Star & Planet Format, Globe Inst, DK-1350 Copenhagen, Denmark 18.Univ Bayreuth, Bayer Geoinst, D-95447 Bayreuth, Germany 19.Univ Paris Cite, Inst Phys Globe Paris, F-75005 Paris, France 20.Seoul Natl Univ, Dept Earth Sci Educ, Seoul 08826, South Korea 21.Univ Chicago, Dept Geophys Sci, Chicago, IL 60637 USA 22.Univ Chicago, Enrico Fermi Inst, Chicago, IL 60637 USA 23.Ibaraki Univ, Fac Sci, Mito 3108512, Japan 24.Inst Space & Astronaut Sci ISAS, Japan Aerosp Explorat Agcy JAXA, Sagamihara, Kanagawa 2525210, Japan 25.Univ Tokyo, Dept Gen Syst Studies, Tokyo 1530041, Japan 26.Nagoya Univ, Dept Earth & Planetary Sci, Nagoya 4648601, Japan 27.Max Planck Inst Chem, D-55128 Mainz, Germany 28.Univ Tokyo, Dept Earth & Planetary Sci, Tokyo 1130033, Japan 29.Univ Queensland, Sch Earth & Environm Sci, St Lucia, Qld 4072, Australia 30.Kyoto Univ, Div Earth & Planetary Sci, Kyoto 6068502, Japan 31.Univ Wisconsin Madison, Dept Geosci, Madison, WI 53706 USA 32.Max Planck Inst Solar Syst Res, D-37077 Gottingen, Germany 33.Univ Calif Los Angeles, Dept Earth Planetary & Space Sci, Los Angeles, CA 90095 USA 34.Natl Aeronaut & Space Adm Johnson Space Ctr, Astromat Res & Explorat Sci Div, Houston, TX 77058 USA 35.Univ Gottingen, Fac Geosci & Geog, D-37077 Gottingen, Germany 36.Korea Polar Res Inst, Div Earth Syst Sci, Incheon 21990, South Korea 37.Univ Lorraine, Ctr Natl Rech Sci Univ Lorraine, Ctr Natl Rech Sci, F-54500 Nancy, France 38.Univ Sci & Technol China, Sch Earth & Space Sci, Hefei 230026, Anhui, Peoples R China 39.Nat Hist Museum, Dept Earth Sci, London SW7 5BD, England 40.Hokkaido Univ, Isotope Imaging Lab, Sapporo, 0010021, Japan 41.Swiss Fed Inst Technol, Inst Geochem & Petrol, Dept Earth Sci, CH-8092 Zurich, Switzerland 42.Osaka Univ, Dept Earth & Space Sci, Osaka 5600043, Japan 43.Arizona State Univ, Sch Earth & Space Explorat, Tempe, AZ 85281 USA 44.Univ Maryland, Dept Geol, College Pk, MD 20742 USA 45.Okayama Univ, Grad Sch Nat Sci & Technol, Okayama 7008530, Japan 46.Univ Calif Davis, Dept Earth & Planetary Sci, Davis, CA 95616 USA 47.Dept Sci & Engn, Natl Museum Nat & Sci, Tsukuba 3050005, Japan 48.Nanjing Univ, Sch Earth Sci & Engn, Nanjing 210023, Peoples R China 49.Tohoku Univ, Dept Earth Sci, Sendai 9808578, Japan 50.Kyushu Univ, Dept Earth & Planetary Sci, Fukuoka 8190395, Japan 51.Hiroshima Univ, Earth & Planetary Syst Sci Program, Higashihiroshima, Japan 52.Kanagawa Inst Technol, Grad Sch Engn, Atsugi 2430292, Japan 53.Univ Tokyo, UTokyo Org Planetary & Space Sci UTOPS, Tokyo 1130033, Japan |
| Recommended Citation GB/T 7714 | Morita, Mayu,Yui, Hiroharu,Urashima, Shu-hei,et al. Analysis of Cation Composition in Dolomites on the Intact Particles Sampled from Asteroid Ryugu[J]. ANALYTICAL CHEMISTRY,2023,96(1):170-178. |
| APA | Morita, Mayu.,Yui, Hiroharu.,Urashima, Shu-hei.,Onose, Morihiko.,Komatani, Shintaro.,...&Yurimoto, Hisayoshi.(2023).Analysis of Cation Composition in Dolomites on the Intact Particles Sampled from Asteroid Ryugu.ANALYTICAL CHEMISTRY,96(1),170-178. |
| MLA | Morita, Mayu,et al."Analysis of Cation Composition in Dolomites on the Intact Particles Sampled from Asteroid Ryugu".ANALYTICAL CHEMISTRY 96.1(2023):170-178. |
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