GIG OpenIR  > 中国科学院矿物学与成矿学重点实验室
Chen, Meng1,2; Zhu, Runliang1,2,3; Zhu, Jianxi1,2,3; He, Hongping1,2,3
Percolation of Low-Dimensional Water at Crystalline Interfaces Mediates Fluid Migration in Subducting Slabs
Source PublicationJOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH
ISSN2169-9313
2023-09-01
Volume128Issue:9Pages:16
DOI10.1029/2023JB027124
Language英语
WOS Research AreaGeochemistry & Geophysics
AbstractDuring subduction, metamorphic dehydration reactions in the downgoing slab release fluids, generating fluid overpressure. It has been suggested that fluid is driven to flow upward by buoyancy, but a sufficiently high permeability allowing formation of a fluid percolation network is required. Traditionally, fluid percolation has been identified based on the textural equilibrium assumption by measuring the dihedral angle at the triple junction of grains. According to this theory, grain boundaries generally cannot be infiltrated by fluid, and only the grain edge can form a fluid flow channel. We argue that this theory is insufficient because we have found that water from fluid can be adsorbed into the crystalline interface, that is, a layered mineral interlayer, a crack, or a grain boundary. The high pressure in a subducting slab drives water adsorption into the crystalline interface, forming a low-dimensional fluidic phase, and thus fluid percolation is achieved. Because water adsorbed in the interface is fluidic, water diffusion drives fluid transport in the subducting slab. Due to water adsorption, fluid overpressure at the dehydration front may release, so that dehydration embrittlement may be excluded. Stable water adsorption in the subduction-slab conditions is determined here by combining molecular dynamics simulations and thermodynamic calculations. Analysis based on simulations shows that water adsorption requires crystalline surfaces which do not form hydrogen bonds well.
Keywordhydrous mineral molecular simulation thermodynamics high pressure phyllosilicate water
WOS IDWOS:001064404500001
Indexed BySCI
Citation statistics
Document Type期刊论文
Identifierhttp://ir.gig.ac.cn/handle/344008/74811
Collection中国科学院矿物学与成矿学重点实验室
Corresponding AuthorChen, Meng
Affiliation1.Chinese Acad Sci, CAS Key Lab Mineral & Metallogeny, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou Inst Geochem,Inst Earth Sci, Guangzhou, Peoples R China
2.CAS Ctr Excellence Deep Earth Sci, Guangzhou, Peoples R China
3.Univ Chinese Acad Sci, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Chen, Meng,Zhu, Runliang,Zhu, Jianxi,et al. Percolation of Low-Dimensional Water at Crystalline Interfaces Mediates Fluid Migration in Subducting Slabs[J]. JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH,2023,128(9):16.
APA Chen, Meng,Zhu, Runliang,Zhu, Jianxi,&He, Hongping.(2023).Percolation of Low-Dimensional Water at Crystalline Interfaces Mediates Fluid Migration in Subducting Slabs.JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH,128(9),16.
MLA Chen, Meng,et al."Percolation of Low-Dimensional Water at Crystalline Interfaces Mediates Fluid Migration in Subducting Slabs".JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH 128.9(2023):16.
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