GIG OpenIR  > 中国科学院矿物学与成矿学重点实验室
Wang, Mengxi1,2; Zhang, Buqian1; Li, Zhongzhou1; Wang, Jie2,3; Wang, Jiangze2,3
In situ crystallization of Fe-Ti oxides in the Bijigou layered intrusion: Insights from crystal size distributions and compositions of magnetite and ilmenite
Source PublicationJOURNAL OF ASIAN EARTH SCIENCES
ISSN1367-9120
2023-10-01
Volume255Pages:17
DOI10.1016/j.jseaes.2023.105773
Language英语
WOS Research AreaGeology
AbstractThe formation of Fe-Ti oxide ore bodies in layered intrusions is attributed to in situ crystallization of basaltic magmas or accumulation after crystal settling regardless of their thicknesses and occurrences in the intrusion. These two key processes are difficult to be distinguished in terms of chemical compositions of minerals or cumulates. However, the crystal size distributions (CSDs) of Fe-Ti oxides in the rocks can be remarkably distinct in these two processes. In this study, we collected samples from a drill core profile across the major Fe-Ti oxide-rich segment of the Bijigou intrusion, a large and differentiated layered intrusion in Central China, and carried out a detailed study on the CSDs and in situ major and trace elements of magnetite and ilmenite to examine how Fe-Ti oxides are accumulated to form Fe-Ti oxide ore bodies in the intrusion. The major Fe-Ti oxide-rich segment of the intrusion consists of, from the base upward, a Fe-Ti oxide ore layer (-80 m), a troctolite unit (-105 m), an oxide gabbro unit (-153 m) and an apatite-oxide gabbronorite unit (-165 m). Large grains of magnetite and ilmenite in the Fe-Ti oxide ore layer show logarithmic-linear CSD curves, similar to those yielded by in situ crystallization of Fe-Ti oxides. The modes of Fe-Ti oxides in the oxide gabbro unit and apatite-oxide gabbronorite unit fluctuate along the profile, which cannot be attributed to accumulation after crystal settling. In addition, the magnetite of the Fe-Ti oxide ore layer, oxide gabbro unit and apatite-oxide gabbronorite unit shows a gentle increase trend of Cr concentration from the base upward in each unit, inconsistent with the trend for an accumulation after crystal settling. The magnetite grains enclosed within silicates have similar compositions to those interstitial to silicates, indicating that they all crystallized from similarly interstitial Fe-rich melt. The in situ crystallization of Fe-Ti oxides is likely triggered by increasing oxygen fugacity due to dissociation of H2O in highly evolved interstitial liquid that was expelled from underlying crystal mush. The crystallization of low-Cr magnetite at the base of each unit is attributed to suppressed eddy currents by dramatic increase of latent heat of crystallization in the magmas at the base. The eddy currents may gradually become efficient toward the top of the magmas due to rapid dissipation of latent heat of crystallization in the magmas, leading to crystallization of high-Cr magnetite by ion diffusion on the top of each unit. This study also demonstrates that analysis of CSDs for Fe-Ti oxides is applicable to examine the accumulation mechanism of Fe-Ti oxide ore bodies in layered intrusions.
KeywordIn situ crystallization Oxygen fugacity Chromium concentration Fe-Ti oxides Layered intrusions
WOS IDWOS:001036292600001
Indexed BySCI
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.gig.ac.cn/handle/344008/74569
Collection中国科学院矿物学与成矿学重点实验室
Corresponding AuthorWang, Mengxi
Affiliation1.Changan Univ, Sch Earth Sci & Resources, Xian 710054, Peoples R China
2.Guangzhou Inst Geochem, CAS Key Lab Mineral & Metallogeny, Guangzhou 510640, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Mengxi,Zhang, Buqian,Li, Zhongzhou,et al. In situ crystallization of Fe-Ti oxides in the Bijigou layered intrusion: Insights from crystal size distributions and compositions of magnetite and ilmenite[J]. JOURNAL OF ASIAN EARTH SCIENCES,2023,255:17.
APA Wang, Mengxi,Zhang, Buqian,Li, Zhongzhou,Wang, Jie,&Wang, Jiangze.(2023).In situ crystallization of Fe-Ti oxides in the Bijigou layered intrusion: Insights from crystal size distributions and compositions of magnetite and ilmenite.JOURNAL OF ASIAN EARTH SCIENCES,255,17.
MLA Wang, Mengxi,et al."In situ crystallization of Fe-Ti oxides in the Bijigou layered intrusion: Insights from crystal size distributions and compositions of magnetite and ilmenite".JOURNAL OF ASIAN EARTH SCIENCES 255(2023):17.
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